The first example of macrocycles containing butterfly transition metal cluster cores via novel tandem reactions |
| |
Authors: | Song Li-Cheng Fan Hong-Tao Hu Qing-Mei |
| |
Institution: | Department of Chemistry and the State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China. |
| |
Abstract: | A novel type of double butterfly, two mu-CO-containing dianions {(mu-CO)Fe2(CO)6]2mu-SCH2(CH2OCH2)nCH2S-mu]}2- (m1, n = 2, 3), has been synthesized from dithiol HSCH2(CH2OCH2)nCH2SH (n = 2, 3), Fe3(CO)12, and Et3N in THF at room temperature. While dianions m1 react in situ with CS2 followed by treatment with dihalide 1,4-(BrCH2)2C6H4 or 1,4-I(CH2)4I to give macrocyclic clusters mu-SCH2(CH2OCH2)nCH2S-mu](mu-CS2ZCS2-mu)Fe2(CO)6]2 (1a, n = 2, Z = 1,4-(CH2)2C6H4; 1b, n = 3, Z = (CH2)4), reactions of dianions m1 with (mu-S2)Fe2(CO)6 followed by treatment with dihalide 1,4-I(CH2)4I afford macrocyclic clusters mu-SCH2(CH2OCH2)nCH2S-mu]{Fe2(CO)6]2(mu4-S)}2mu-S(CH2)4S-mu] (2a, n = 2; 2b, n = 3). The crystal structures of 1a and 2b are described. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|