Surface interaction of ethylene glycol with silver |
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Authors: | O V Vodyankina L N Kurina and G A Izatulina |
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Institution: | (1) Tomsk State University, 634050 Tomsk, Russia |
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Abstract: | Interaction of ethylene glycol with clean and oxidized surfaces of an Ag catalyst has been studied under pre-catalysis conditions.
On a clean surface, ethylene glycol was reversibly adsorbed with the formation of a multilayer coverage. Adsorbed ethylene
glycol weakly bonded to the oxidized silver surface leads to the selective formation of glyoxalvia two parallel routes: dehydrogenation and oxidation. Dissociative interaction of ethylene glycol with Ag led to the appearance
of formaldehyde and carbon dioxide by-products. |
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Keywords: | Ethylene glycol glyoxal silver oxidation dehydrogenation |
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