Novel titanium complexes of a multidentate dicarbollide ligand. Synthesis and structural characterization of a constrained geometry complex |
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| Authors: | Lee Young-Joo Lee Jong-Dae Ko Jaejung Kim Sang-Hern Kang Sang Ook |
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| Institution: | Department of Chemistry, Korea University, 208 Seochang, Chochiwon, Chung-nam 339-700, Korea. |
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| Abstract: | The multidentate dicarbollide ligand nido-7,8-(NMe2CH2)2-7,8-C2B9H11 has been prepared, structurally characterized, and employed in the preparation of the novel mono- and trimetallic titanium complexes eta5:eta1-(NMe2CH2)C2B9H9CH2NMe2]Ti(NMe2)2 and eta5:eta1-(NMe2CH2)C2B9H9CH2NMe2]Ti(NMe2)]2-mu3-O-Ti(NMe2)2. |
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