60]- and [70]Fullerenes are trifluoromethylated across 5:6-bonds |
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| Authors: | Darwish Adam D Avent Anthony G Abdul-Sada Ala'a K Taylor Roger |
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| Affiliation: | The Chemistry Laboratory, CPES School, University of Sussex, Brighton, UK BN1 9QJ. |
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| Abstract: | Trifluoromethylation of [60]- and [70]fullerenes occurs across both 6:6- and 5:6-bonds giving unsymmetrical tetramethyl adducts having four contiguous CF3 groups; both fullerenes give bis adducts which do not involve 6:6-addition, and unsymmetrical hexa-adducts (with contiguous CF3 groups) are also obtained from [60]fullerene. |
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