Room-temperature ionic liquids as new solvents for organic electrosynthesis. The first examples of direct or nickel-catalysed electroreductive coupling involving organic halides |
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Authors: | Barhdadi Rachid Courtinard Coralie Nédélec Jean Yves Troupel Michel |
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Institution: | Laboratoire d'Electrochimie Catalyse et Synthèse Organique (UMR 7582), CNRS-Université Paris 12 Val de Marne, 2 rue Henry Dunant, 94320 Thiais, France. barhdadi@glvt-cnrs.fr |
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Abstract: | Direct or Ni-catalysed electroreductive homocouplings of organic halides and couplings of organic halides with activated olefins are efficiently conducted by constant current electrolyses in an undivided cell in room-temperature ionic liquids as the solvent-electrolyte media. |
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