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A new cationic,chiral catalyst for highly enantioselective Diels-Alder reactions |
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| Authors: | Sprott Kevin T Corey E J |
| Institution: | Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA. |
| Abstract: | reaction: see text] The Diels-Alder reaction of cyclopentadiene and 2-methacrolein is catalyzed by a chiral Lewis acid to form the exo adduct in 96% yield and 96% ee. |
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