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Functionalizing the surface of II-VI clusters: redox active centres on the adamantoid complex [Cd4Cl4[mu-(SeC5H4)Fe(C5H5)]6]2-
Authors:Lebold Terry P  Stringle Donald L B  Workentin Mark S  Corrigan John F
Institution:Department of Chemistry, The University of Western Ontario, London N6A 5B7, Canada.
Abstract:Trimethylsilylselenoferrocene 1 has been prepared in good yield. The reactive silyl group on 1 is used as a driving force for the synthesis Cl4Cd4mu2-Se(C5H4)Fe(C5H5))6]2- 2, a Cd4Se6 adamantoid cluster with six surface ferrocenyl groups.
Keywords:
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