The behaviour of some α,α′-dibromoketones on electron impact. An analogy to the reductive removal of bromine in solution |
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Authors: | H M R Hoffmann A G Loudon |
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Abstract: | The relative importance of the rearrangement ions M ? Br ? CO]+, M ? Br2 ? CO]+ and M ? HBr2 ? CO]+ in the mass spectra of the title compounds is compared with the amounts of α-methoxyketone formed on reduction of these compounds with a Zn/Cu couple in methanol. It is suggested that the quantitative correlation found reflects the electron releasing powers of the substituents on the α carbons. |
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