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Free radicals in γ-irradiated poly-α-methylstyrene
Authors:Sheila Mawaziny  Salah Arafa  Magdy F Iskandar  Maher Z El-Subee
Abstract:Electron spin resonance (ESR) spectra were observed at ?160°C and at room temperature for γ-irradiated poly-α-methylstyrene. The spectrum observed at room temperature has been attributed to the radical species equation image while that at ?160°C results from the same radical and superposition of the spectrum due to the radical ?H2-C(CH3)(C6H5)-. The radicals which are stable at room temperature could be used to graft vinyl acetate.
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