Dual role of azide in the formation of a 3D coordination polymer containing bridging 5-pyrimidinecarboxylate |
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Authors: | Sengupta Oindrila Chakrabarty Rajesh Mukherjee Partha Sarathi |
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Institution: | Inorganic and Physical Chemistry Department, Indian Institute of Science, Bangalore, 560012, India. |
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Abstract: | A new 3D framework Mn4(5-pmc)4(1,1-N3)4]n () composed of a rare MnII4 square as the repeating secondary building unit, representing the first coordination polymer of 5-pyrimidinecarboxylate (5-pmc) has been successfully synthesized and characterized by X-ray single crystal structure analysis. |
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