| 钼铁硫络合物晶体的合成、结构和性质研究 |
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| 引用本文： | 张致贵,王凤山,李淑琴,赵承志,李英.钼铁硫络合物晶体的合成、结构和性质研究[J].高等学校化学学报,1984,5(2):276. |
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| 作者姓名： | 张致贵 王凤山 李淑琴 赵承志 李英 |
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| 作者单位： | 1. 吉林大学化学系;
2. 吉林大学理化所 |
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| 摘 要： | 近几年来,模拟固氮酶的活性中心--钼铁硫原子簇化合物的合成、结构和性质研究,引起人们极大的兴趣.本文研究了一种新型的钼铁硫络合物晶体的合成、结构和性质。
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| 收稿时间： | 1982-10-06 |
STUDIES ON THE SYNTHESIS,STRUCTURE AND PROPERTIES OF THE CRYSTAL OF Mo-Fe-S COMPLEX |
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| Zhang Zhigui,Wang Fengshan,Li Shuqin,Zhao Chengzhi,Li Ying.STUDIES ON THE SYNTHESIS,STRUCTURE AND PROPERTIES OF THE CRYSTAL OF Mo-Fe-S COMPLEX[J].Chemical Research In Chinese Universities,1984,5(2):276. |
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| Authors: | Zhang Zhigui Wang Fengshan Li Shuqin Zhao Chengzhi Li Ying |
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| Institution: | 1. Department of Chemistry, Jilin University, Changchun;
2. Institute of Theoretical Chemistry, Jilin University, Changchun |
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| Abstract: | In this paper, we report a new complex of Mo-Fe-Ssynthesized by the reaction of MoCl5, FeCl2·4H2O, PhCH2SH and diethyldithiocarba-mate(DTC) in MeOH, The complex is characterized by X-ray crystal-lography,IR,UV-visible, 1H NMR, 13C NMR, and EPRspectra, and the measurements of elemental analyses and electrochemical properties. The crystal of Mo-Fe-Scomplex containing multi-bond species is quite stable. |
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