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Catalytic enantioselective conjugate additions using enantiopure β-amino disulfides and β-amino thiolates |
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| Authors: | Colin L Gibson |
| Institution: | Department of Pure & Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow, G1 1XL, UK |
| Abstract: | The enantioselective conjugate addition of diethylzinc to chalcone catalysed by nickel(II) using an enantiopure β-amino thiolate 2 or β-amino disulfide 1 to achieve ee's of up to 50% is described. |
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