N-labelling studies of the reaction of 2,6-di-t-butyl-4-methyl-4-nitrocyclohexa-2,5-dienone with nitrogen dioxide; A revised mechanism |
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Authors: | Michael P. Hartshorn Richard G. Jensen A. Grant Waller Graeme J. Wright |
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Affiliation: | Department of Chemistry, University of Canterbury, Christchurch, New Zealand |
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Abstract: | Reaction of the 15N-4-nitrodienone (1) with excess nitrogen dioxide in benzene for 16 h gives the 4,5,6-trinitro ketone (2), labelled (15NO2) at C6 but not at C4, and recovered 4-nitrodienone (1) in which extensive loss of 15NO2 has occurred. The mechanistic implications of these and related results are discussed. |
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