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Enantioselective hydrogenations with chiral titanocenes
Authors:Vassylyev Oleksiy  Panarello Anthony  Khinast Johannes G
Institution:Department of Chemical and Biochemical Engineering, Rutgers University, Piscataway, NJ 08854-8058, USA.
Abstract:In this review article chiral titanocenes and their application for the enantioselective hydrogenations of different unsaturated compounds are discussed, with a special emphasis on the kinetics and the practicality of the developed systems. The nature of enantioselectivity and the hydrogenation mechanisms are reviewed as well. Catalyst immobilization and the different immobilization techniques are examined.
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