Microwave-assisted, Pd(0)-catalyzed cross-coupling of diazirines with aryl halides |
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| Authors: | Zhao Xia Wu Guojiao Yan Chong Lu Kui Li Hui Zhang Yan Wang Jianbo |
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| Affiliation: | Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China. |
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| Abstract: | Pd(0)-catalyzed cross-coupling reactions of diazirines with aryl halides under microwave heating conditions afford a series of substituted olefins. A reaction mechanism involving the migratory insertion of the Pd carbene intermediate is proposed. |
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