Copper-catalyzed arylation of 1H-perfluoroalkanes |
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| Authors: | Popov Ilya Lindeman Sergey Daugulis Olafs |
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| Institution: | Department of Chemistry, University of Houston, Houston, Texas 77204-5003, USA. |
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| Abstract: | A general method has been developed for arylation of readily available 1H-perfluoroalkanes. The method employs aryl iodide and 1H-perfluoroalkane reagents, DMPU solvent, TMP(2)Zn base, and a copper chloride/phenanthroline catalyst. Preliminary mechanistic studies are reported. |
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