Total synthesis of the originally proposed and revised structures of scleritodermin A |
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| Authors: | Liu Sheng Cui Yong-Mei Nan Fa-Jun |
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| Institution: | Chinese National Center for Drug Screening, State Key Laboratory of Drug Research Shanghai Institute of Materia Medica, Chinese Academy of Sciences 189 Guoshoujing Road, Zhangjiang Hi-Tech Park, Shanghai 201203,China. |
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| Abstract: | The first total synthesis of the originally proposed and revised structure of scleritodermin A, along with an isomer, were achieved by the use of an alpha-azido carboxyl group serving as the key alpha-ketoamide precursor, thus leading to a revision of the structure originally proposed for natural scleritodermin A. |
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