A Gas-phase study of the preferential solvation of Mn2+ in mixed water/methanol clusters |
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| Authors: | Bridgette J. Duncombe Jens O. S. Rydén Ljilijana Puškar Hazel Cox Anthony J. Stace |
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| Affiliation: | Department of Physical Chemistry, School of Chemistry, University of Nottingham, University Park, Nottingham, UK. |
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| Abstract: | The kinetic shift that exists between two competing unimolecular fragmentation processes has been used to establish whether or not gas-phase Mn(2+) exhibits preferential solvation when forming mixed clusters with water and methanol. Supported by molecular orbital calculations, these first results for a metal dication demonstrate that Mn(2+) prefers to be solvated by methanol in the primary solvation shell. |
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