Condensed metallaborane clusters: synthesis and structure of Fe2(CO)6(eta5-C5Me5RuCO)(eta5-C5Me5Ru)B6H10 |
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| Authors: | Ghosh Sundargopal Fehlner Thomas P Noll Bruce C |
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| Institution: | Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556, USA. sghosh@nd.edu |
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| Abstract: | Mild pyrolysis of (eta5-C5Me5Ru)2B6H12 with Fe2(CO)9 yields the 12 skeletal electron pair (sep) Fe2(CO)6(eta5-C5Me5RuCO)(eta5-C5Me5Ru)B6H10 cluster; the title compound represents a novel class of hybrid multiple cluster in which a Fe2B2 tetrahedron has been fused to a ruthenaborane substrate. |
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