| CF2HCl分子在红外多光子解离时分子间的能量传递过程 |
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| 引用本文： | 习宁,顾镇南.CF2HCl分子在红外多光子解离时分子间的能量传递过程[J].物理化学学报,1989,5(4):388-391. |
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| 作者姓名： | 习宁 顾镇南 |
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| 作者单位： | Department of Chemistry; Peking University |
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| 摘 要： |
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| 关 键 词： | CF2HC1 红外光子解离 能量传递 |
| 收稿时间： | 1989-01-23 |
| 修稿时间： | 1989-03-02 |
ENERGY TRNANSFER IN IR MPD CF2HCI |
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| Xi Ning,Gu Zhennan.ENERGY TRNANSFER IN IR MPD CF2HCI[J].Acta Physico-Chimica Sinica,1989,5(4):388-391. |
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| Authors: | Xi Ning Gu Zhennan |
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| Institution: | Department of Chemistry; Peking University |
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| Abstract: | The infrared multiphoton dissociation (IR MPD) of CF_2HCl by measuring the C_2F_4 product after laser irradiation is investigated, The dissociation fraction of CF_2HCl as a function of the CF_2HCl pressure, laser energy fluence and number of laser pulses is measured. Under the low pressure condition the bottleneck effect is observed. Under the collision condition the dissociation fraction of CF_2HCl is affected by the competition between rotaional hole filling (collisional repoputation of pumped rotational states) and collisional deactivation of excited CF_2HCl moleculae. |
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