Kinetics and Mechanism of Dehydration of Heteropolyacids |
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| Authors: | V. V. Khakhinov L. V. Tumurova |
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| Affiliation: | (1) Siberian Department of Russian Academy of Sciences, Buryat Institute of Natural Sciences, 670042 Ulan-Ude, Russian Federation |
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| Abstract: | The kinetics and mechanism of the dehydration and decomposition of heteropolyacids of molybdenum, tungsten and vanadium (H3+xYx+M12O40·mH2O; Y=Si, P; M=Mo, W) were studied. The data obtained on the dehydration kinetic parameters correlate with the expected structures, of these crystal hydrates, the IR data and X-ray phase analysis. This revised version was published online in July 2006 with corrections to the Cover Date. |
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| Keywords: | decomposition dehydration kinetics |
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