Synthesis and crystal structure of maleonitriledithiolate metal complexes with N-methylacridine as cations |
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| Institution: | 1. Department of Chemistry, Ferdowsi University of Mashhad, 917751436 Mashhad, Islamic Republic of Iran;2. Departament de Química, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, 07122 Palma de Mallorca (Baleares), Spain;3. Department of Chemistry, Tulane University, New Orleans, LA 70118, USA;1. Radioanalytical Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India;2. Homi Bhabha National Institute, Anushaktinagar, Mumbai 400094, India;3. Chemical Engineering Division, Bhabha Atomic Research Centre, Mumbai 400085, India;1. State Key Laboratory for Novel Software Technology, Nanjing University, China;2. School of Computer Science and Information Technology, RMIT University, Australia;1. Fiber and Polymer Science Program, NC State University, Raleigh, NC 27695, USA;2. Department of Physics, NC State University, Raleigh, NC 27695, USA |
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| Abstract: | The synthesis of N-MeA]2M(mnt)2] (N-MeA=N-methylacridine; M=Ni (II), Zn (II), Cu (II) and Cd (II); mnt=maleonitriledithiolate) and crystal structure analysis of the Ni (1) and Zn (2) complexes are reported. The conductivities of almost all the complexes under 4 MPa pressure are above 10?5 S cm?1, which are characteristic of intrinsic semi-conductors. The complexes exhibit charge transfer transitions in both their absorption spectra and fluorescence spectroscopy. |
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