The syntheses,crystal, molecular and electronic structures of two polymorphs of [ReCl2(N2COPh)(C3N2H4)(PPh3)2] and [ReCl2(N2COPh)(py)(PPh3)2] complexes |
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| Institution: | 1. Department of Inorganic and Radiation Chemistry, Institute of Chemistry, University of Silesia, 9th Szkolna St., 40-006 Katowice, Poland;2. X-ray Crystallography Laboratory, Institute of General and Ecological Chemistry, Technical University of Łódź, 116 Żeromski St., 90-924 Łódź, Poland;3. Institute of Physics, University of Silesia, 4th Uniwersytecka St., 40-006 Katowice, Poland;1. University of Kurdistan, Department of Chemistry, Faculty of Science, Sanandaj, Iran;2. Department of Chemistry, Faculty of Science, Ilam University, P.O. Box, 69315516 Ilam, Iran;1. Department of Chemical Engineering and Food Processing, Xuancheng Campus, Hefei University of Technology, Xuancheng, 242000 Anhui, PR China;2. Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials (CEM), School of Environmental Sciences and Engineering, Nanjing University of Information Science and Technology, Nanjing 210044, Jiangsu, PR China;3. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, PR China;1. Department of Chemistry, Payame Noor University (PNU), 19395-4697 Tehran, Iran;2. Department of Crystallography, Institute of Chemistry, University of Silesia, ul. Szkolna 9, 40-006 Katowice, Poland;1. Holzforschung Austria, Franz-Grill-Strasse 7, 1030 Vienna, Austria;2. Institute of Wood Science and Technology, University of Natural Resources and Life Sciences, Konrad-Lorenz-Straße 24, 3430 Tulln an der Donau, Austria;1. Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China;2. School of Chemistry and Chemical Engineering, Anhui Province Key Laboratory of Functional Optical, Electrical and Magnetic Materials, Key Laboratory of Functional Coordination Compounds and Nano Materials of Anhui Higher Education Institutes, Anqing Normal University, Anqing 246011, China |
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| Abstract: | The ReCl2(η2-N2COPh–N′,O)(PPh3)2] complex reacts with pyridine and pyrazole to give ReCl2(N2COPh)(py)(PPh3)2] and ReCl2(N2COPh)(C3N2H4)(PPh3)2], respectively. Two monoclinic polymers of ReCl2(N2COPh)(C3N2H4)(PPh3)2] and ReCl2(N2COPh)(py)(PPh3)2] have been characterized by IR, UV–Vis, 1H NMR, magnetic measurements and X-ray structure. |
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