Acidic isomerization of alantolactone derivatives |
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Authors: | S G Klochkov S V Afanaséva A N Pushin |
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Institution: | (1) Institute of Physiologically Active Compounds, Russian Academy of Sciences, 142432 Moscow Region, Noginsk District, Chernogolovka, Severnyi proezd, 1 |
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Abstract: | A series of derivatives of the natural sesquiterpene lactones alantolactone (1) and isoalantolactone (2) was prepared. The α-methylene-γ-lactone moiety was retained in the structures of these for further modifications using reactions
that affected exclusively the nonconjugated double bonds of the decalin ring.
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Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 325–330, July–August, 2006. |
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Keywords: | sesquiterpene lactones alantolactone isoalantolactone acidic isomerization Inula helenium L |
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