Toluates: unexpectedly versatile reagents |
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| Authors: | Kevin Lam |
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| Institution: | Département de Chimie, Bâtiment Lavoisier, Université catholique de Louvain, Place Louis Pasteur, 1B-1348 Louvain-la-Neuve, Belgium |
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| Abstract: | The mechanism of the monoelectronic reduction of aromatic esters has been investigated. The unexpected synthetic utility of the toluate moiety in the deoxygenation of alcohols and the allylation of ketones is also reported. Finally, the use of aromatic esters as robust, though easily removable, protecting groups is depicted. |
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