Regioselective synthesis of amino- and nitroarenes based on [3+3] cyclocondensations of 1,3-bis(silyloxy)-1,3-butadienes |
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| Authors: | Abdolmajid Riahi Mohanad Shkoor Mirza A Yawer Christine Fischer |
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| Institution: | a Institut für Chemie, Universität Rostock, Albert-Einstein-Str. 3a, 18059 Rostock, Germany
b Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany |
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| Abstract: | Functionalized amino- and nitro-substituted biaryls and dibenzob,d]pyrid-6-ones (6(5H)-phenanthridinones) were prepared by 3+3]cyclocondensation of 1,3-bis(trimethylsilyloxy)-1,3-butadienes with nitro-substituted 1-aryl-1-silyloxy-1-en-3-ones and subsequent hydrogenation. 4-Nitro- and 4-aminophenols were prepared based on formal 3+3] cyclizations of 1,3-bis(trimethylsilyloxy)-1,3-butadienes with 3-ethoxy-2-nitro-2-en-1-ones. |
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| Keywords: | Arenes Cyclizations Nitro compounds Regioselectivity Silyl enol ethers |
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