Synthesis of amides through the Cannizzaro-type reaction catalyzed by lanthanide chlorides |
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| Authors: | Lijun Zhang |
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| Institution: | Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, Institute of Organic Chemistry, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China |
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| Abstract: | Amidation of aldehydes with lithium amides through the LnCl3-catalyzed Cannizzaro-type reactions afforded a variety of amides in high yields. The electronic and steric effects on the reaction were investigated. The features of the economical catalysts, high yields, tolerance of a wide range of lithium amides and aromatic aldehydes make this methodology an easy and valid contribution to the direct synthesis of amides from aldehydes. |
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