Synthesis and catalytic properties of rhodium(I) complexes with anionic chelate nitrogen-oxygen ligands |
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| Authors: | Wanzhi Chen Yun Xu Shijian Liao |
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| Institution: | (1) Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023 Dalian, P.R. China;(2) Present address: Institute of New Materials, Shandong University, 250100 Jinan, Shandong, P.R. China |
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| Abstract: | Summary Dicarbonyl complexes of rhodium(I) Rh(CO)2(LL )], where LL = salicylaldoximate, 8-oxyquinolinate, glycinate, leucinate, aminophenolate or pyridine carboxylate and Rh(COD)(LL)], where COD = 1,5-cyclooctadiene, were prepared and characterized by elemental analysis, and i.r. and n.m.r. spectra. Their activity to catalytic hydroformylation of styrene has been evaluated at atmospheric pressure of CO H2(11). |
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