Synthesis and X-ray analysis of (RS)-N-tert-butyl-2-anilino- |
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| Authors: | Joseph H Reibenspies Erach R Talaty Mashitah M Yusoff |
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| Institution: | (1) Department of Chemistry, Texas A & M University, 77845 College Station, Texas;(2) Department of Chemistry, Wichita State University, 67260-0051 Wichita, Kansas |
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| Abstract: | The crystal and molecular structure of (RS)-N-Tert-butyl-2-anilino-3,3-dimethylbutanamide, a derivative of an amino acid that was obtained by highly selective cleavage of 1,3-di-tert-butylaziridinone by aniline, is described. The racemic mixture of the amide crystallizes in the space groupP 21/n with four molecules per unit cell. Crystal Data:a=10.483(2) Å,b=6.206(1) Å,c=24.767(5) Å,β=90.39(3),V=1611.5(6) A3,R(F)I>2σ(I)]=0.0679.wR(F 2) I>2σ(I)]=0.1148. |
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| Keywords: | Crystal structure selectivity in ring-opening of an aziridinone |
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