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On the Reactivity of (7‐Oxabicyclo[2.2.1]hept‐5‐en‐2‐ylidene)amines. Different Reaction Paths Leading to the Same Final Products |
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| Authors: | Odn Arjona Aurelio&#x;G Cskÿ M&#x;Carmen Murcia Joaquín Plumet |
| Abstract: | The reaction of amines, N‐substituted by a 7‐oxabicyclo2.2.1]hept‐5‐en‐2‐ylidene moiety, either with PhSCl or mCPBA (meta‐chloroperbenzoic acid) unexpectedly afforded the same type of furan derivatives by two different reaction paths. The results confirm the intervention of a homoconjugative, electron‐releasing effect of the oxabicycloalkenylideneamine moieties, as predicted theoretically. |
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