Abstract: | 3‐{(tert‐Butoxy)carbonyl]diazenyl}but‐2‐enoates react in tetrahydrofuran at room temperature with aromatic 1,2‐diamines to give 3‐methylquinoxaline‐2‐carboxylates. These products were also obtained in solid‐phase synthesis, by using polymer‐bound 3‐diazenylbut‐2‐enes. |