| The first facile total synthesis of natural （3R,4R,6S）-3, 4-epoxybisabola- 7 （ 14 ）, 10-dien-2-one |
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| 引用本文： | Zhi Yong Tang Chen Xi Zhang,Li Jing Fang,Yu Lin Li. The first facile total synthesis of natural （3R,4R,6S）-3, 4-epoxybisabola- 7 （ 14 ）, 10-dien-2-one[J]. 中国化学快报, 2009, 20(9): 1017-1018. DOI: 10.1016/j.cclet.2009.03.010 |
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| 作者姓名： | Zhi Yong Tang Chen Xi Zhang Li Jing Fang Yu Lin Li |
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| 作者单位： | State Key Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000, China |
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| 基金项目： | supported by the National Science Foundation of China(No.20272021) |
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| 摘 要： |
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| 关 键 词： | 全合成 二烯 天然 简便 中国化学会 BV公司 总收率 烯丙基 |
| 收稿时间： | 2008-12-24 |
The first facile total synthesis of natural (3R,4R,6S)-3,4-epoxybisabola-7(14),10-dien-2-one |
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| Zhi Yong Tang,Chen Xi Zhang,Li Jing Fang,Yu Lin Li State Key Laboratory of Applied Organic Chemistry. The first facile total synthesis of natural (3R,4R,6S)-3,4-epoxybisabola-7(14),10-dien-2-one[J]. Chinese Chemical Letters, 2009, 20(9): 1017-1018. DOI: 10.1016/j.cclet.2009.03.010 |
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| Authors: | Zhi Yong Tang Chen Xi Zhang Li Jing Fang Yu Lin Li State Key Laboratory of Applied Organic Chemistry |
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| Affiliation: | State Key Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000, China |
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| Abstract: | 3,4-Epoxybisabola-7(14),10-dien-2-one,a natural sesquiterpoind,was first synthesized from(-)-carvone through 7 steps,in an overall yield of 35.9%.The key step was the allylation and then a substrate-directable epoxidation was committed successfully. |
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| Keywords: | Alkylation Epoxidation Synthesis |
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