Hexadiene formation during decomposition of 2-propanol over Ca?P?O catalysts |
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Authors: | T Sodesawa |
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Institution: | (1) Department of Industrial Chemistry, Faculty of Engineering, Chiba University, 260 Chiba, Japan |
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Abstract: | Hexadiene formation from 2-propanol was investigated in view of acid-base properties of Ca–P–O catalysts with the Ca/P atomic ratio varying from 1.5 to 5.0. The catalytic activity in hexadiene formation increased up to a maximum at Ca/P=2.0, having almost the same amount of weak acidic sites as weak basic sites, and decreased with futher increase in Ca/P ratio.
![Ocy](/content/x6712316u7w4p151/xxlarge1054.gif) ![bcy](/content/x6712316u7w4p151/xxlarge1073.gif) ![rcy](/content/x6712316u7w4p151/xxlarge1088.gif) ![acy](/content/x6712316u7w4p151/xxlarge1072.gif) ![zcy](/content/x6712316u7w4p151/xxlarge1079.gif) ![ocy](/content/x6712316u7w4p151/xxlarge1086.gif) ![vcy](/content/x6712316u7w4p151/xxlarge1074.gif) ![acy](/content/x6712316u7w4p151/xxlarge1072.gif) ![ncy](/content/x6712316u7w4p151/xxlarge1085.gif) ![icy](/content/x6712316u7w4p151/xxlarge1080.gif) ![gcy](/content/x6712316u7w4p151/xxlarge1075.gif) ![iecy](/content/x6712316u7w4p151/xxlarge1077.gif) ![kcy](/content/x6712316u7w4p151/xxlarge1082.gif) ![scy](/content/x6712316u7w4p151/xxlarge1089.gif) ![acy](/content/x6712316u7w4p151/xxlarge1072.gif) ![dcy](/content/x6712316u7w4p151/xxlarge1076.gif) ![icy](/content/x6712316u7w4p151/xxlarge1080.gif) ![iecy](/content/x6712316u7w4p151/xxlarge1077.gif) ![ncy](/content/x6712316u7w4p151/xxlarge1085.gif) 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![rcy](/content/x6712316u7w4p151/xxlarge1088.gif) ![ocy](/content/x6712316u7w4p151/xxlarge1086.gif) Ca–P–O ![acy](/content/x6712316u7w4p151/xxlarge1072.gif) ![tcy](/content/x6712316u7w4p151/xxlarge1090.gif) ![ocy](/content/x6712316u7w4p151/xxlarge1086.gif) ![mcy](/content/x6712316u7w4p151/xxlarge1084.gif) ![ncy](/content/x6712316u7w4p151/xxlarge1085.gif) ![ycy](/content/x6712316u7w4p151/xxlarge1099.gif) ![ocy](/content/x6712316u7w4p151/xxlarge1086.gif) ![tcy](/content/x6712316u7w4p151/xxlarge1090.gif) ![ncy](/content/x6712316u7w4p151/xxlarge1085.gif) ![ocy](/content/x6712316u7w4p151/xxlarge1086.gif) ![shchcy](/content/x6712316u7w4p151/xxlarge1097.gif) ![iecy](/content/x6712316u7w4p151/xxlarge1077.gif) ![ncy](/content/x6712316u7w4p151/xxlarge1085.gif) ![icy](/content/x6712316u7w4p151/xxlarge1080.gif) ![iecy](/content/x6712316u7w4p151/xxlarge1077.gif) Ca/P, ![icy](/content/x6712316u7w4p151/xxlarge1080.gif) ![zcy](/content/x6712316u7w4p151/xxlarge1079.gif) 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![gcy](/content/x6712316u7w4p151/xxlarge1075.gif) ![acy](/content/x6712316u7w4p151/xxlarge1072.gif) ![mcy](/content/x6712316u7w4p151/xxlarge1084.gif) ![acy](/content/x6712316u7w4p151/xxlarge1072.gif) ![kcy](/content/x6712316u7w4p151/xxlarge1082.gif) ![scy](/content/x6712316u7w4p151/xxlarge1089.gif) ![icy](/content/x6712316u7w4p151/xxlarge1080.gif) ![mcy](/content/x6712316u7w4p151/xxlarge1084.gif) ![ucy](/content/x6712316u7w4p151/xxlarge1091.gif) ![mcy](/content/x6712316u7w4p151/xxlarge1084.gif) ![pcy](/content/x6712316u7w4p151/xxlarge1087.gif) ![rcy](/content/x6712316u7w4p151/xxlarge1088.gif) Ca/P=2, ![kcy](/content/x6712316u7w4p151/xxlarge1082.gif) ![ocy](/content/x6712316u7w4p151/xxlarge1086.gif) ![gcy](/content/x6712316u7w4p151/xxlarge1075.gif) ![dcy](/content/x6712316u7w4p151/xxlarge1076.gif) ![kcy](/content/x6712316u7w4p151/xxlarge1082.gif) ![ocy](/content/x6712316u7w4p151/xxlarge1086.gif) ![lcy](/content/x6712316u7w4p151/xxlarge1083.gif) 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![iecy](/content/x6712316u7w4p151/xxlarge1077.gif) ![ncy](/content/x6712316u7w4p151/xxlarge1085.gif) ![icy](/content/x6712316u7w4p151/xxlarge1080.gif) Ca/P.
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