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Copper(I)---aryl bonds in cluster complexes: The structure of [Cu(2-Me2NH6H4)]4(CuBr)2·1.5C6H6 |
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| Authors: | J M Guss R Mason and K M Thomas G van Koten and J G Noltes |
| Institution: | School of Molecular Sciences, University of Sussex, Brighton BN1 9QJ Great Britain Institute for Organic Chemistry, TNO, Utrecht The Netherlands |
| Abstract: | An X-ray diffraction analysis of Cu(2-Me2NC6H4)]4(CuBr)2·1.5C6H6 shows the six copper atoms in a distorted octahedral arrangement; the bromine atoms bridge trans-equatorial edges, the 2-(dimethylamino)phenyl ligands bridging faces so that the complex has approximate C2 symmetry. |
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