An intramolecular aza-[3+3] annulation approach to azaphenalene alkaloids. Total synthesis of myrrhine |
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| Authors: | Gerasyuto Aleksey I Hsung Richard P |
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| Affiliation: | Division of Pharmaceutical Sciences and Department of Chemistry, University of Wisconsin, Rennebohm Hall, 777 Highland Avenue, Madison, Wisconsin 53705, USA. |
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| Abstract: | A detailed account on the stereoselective total syntheses of azaphenalene alkaloids via an intramolecular aza-[3+3] annulation strategy is described here. All five members of the Coccinellidae family of defensive alkaloids were prepared from the same common intermediate, which was derived from a stereoselective aza-[3+3] annulation reaction. |
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