Investigations into the role of ion pairing in reactions of heteroatom-substituted cyclic oxocarbenium ions |
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Authors: | Shenoy Siddhartha R Woerpel K A |
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Affiliation: | Department of Chemistry, University of California, Irvine, Irvine, California 92697-2025, USA. |
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Abstract: | [reaction: see text] The O-to-C rearrangement of vinyl acetals is used to demonstrate that tight ion pairing is not involved in the stereoselective nucleophilic addition reactions of alkoxy-substituted cyclic oxocarbenium ions. |
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