| Synthesis and Crystal Structure Characterization of [Zr(HPO_4)(PO_4)F_2]·1.5H_3NCH_2CH_2NH_3 |
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| 摘 要： | Thesynthesisofcrystallinezirconiumphosphateswasfirstreportedinl964byClearfieldandStynes'J,whodeterminedtheformulaasZr(HPO,),.H,O(a-ZrP)basedonchemicalcomposition,dehydrationandion-exchangebe-haviour'Sincethen,manyothercrystallinezirconiumphosphate,suchasZr(HPO,)(g-ZrP),Zr(HPO'),.H,O(Y-ZrP),havebeenprepared'.'1.Thesephosphatesconsistedofalternate,cross-linkedlayersofZrO,octahedraandPO'tetrahedrawithwatermoleculesaccommodatedininterlamellarfashion.a-Zirco-niumphosphate,Zr(HPO'),.…
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| 收稿时间： | 1995-08-30 |
Synthesis and Crystal Structure Characterization of [Zr(HPO4)(PO4)F2]·1.5H3NCH2CH2NH3 |
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| Authors: | XU Jia-ning ZHAO Yu-e CHEN Jie-sheng SONG Tian-you XU Ru-ren |
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| Institution: | Department of Chemistry, Jilin University, Changchun, 130023 |
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| Abstract: | The synthesis of crystalline zirconiurn phosphates was first reported in 1964 by Clearfield and Stynes, who determined the tormula as Zr(HPO4) (PO4)F2
(a-Zrp) based on chemical compositiondehydration and ion-exchange be-haviour. Since then, many other crystalline. |
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| Keywords: | Synthesis Crystal structure Zirconium phosphate |
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