Thermal studies on some group VIII complexes with biologically active ligands |
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Authors: | H. S. O. Chan J. R. Lusty |
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Affiliation: | (1) Department of Chemistry, National University of Singapore, 0511 Kent Ridge, Singapore |
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Abstract: | The mode of decomposition of complexes involving biologically important ligands such as thiouracil and xanthine coordinated to some group VIII metals has been studies by thermogravimetry. The results show that the complex tris-(dithiouracil) trichlororhodium(III) is monomeric and not polymeric as suggested previously. The decomposition behavior of the complex indicates that after the initial loss of a ligand molecule to form a four-coordinate complex, further ligand removal takes place in one sharp step. In the case of the complexes bis-(3-methylxanthine) diammineplatinum(II) and bis-(9-methylxanthine) diamminepalladium(II), ammonia comes off first, followed by rapid loss of the remaining xanthine ligands. Moreover, the activation energy determined for the main decomposition step suggests that the breakdown of the xanthine ligand involves the initial cleavage of the pyrimidine moiety, followed closely by loss of the remaining imidazole portion.
Zusammenfassung Die Art der Zersetzung von Komplexen einiger Metalle der VIII. Gruppe mit biologisch wichtigen Liganden, wie Thiouracil and Xanthin, wurde thermogravimetrisch untersucht. Die Ergebnisse zeigen, daß der Komplex Tris-(dithiouracil) trichlororhodium(III) monomer und nicht — wie früher vermutet — polymer ist. Das Zersetzungsverhalten des Komplexes zeigt, daß nach dem zu einem tetrakoordinierten Komplex führenden Verlust eines Ligandmoleküls die Abgabe eines weiteren Liganden in einem scharfen Schritt erfolgt. Im Falle der Komplexe Bis-(3-methylxanthin) diamminplatin(II) und Bis-(9-methylxanthin) diamminpalladium(II) erfolgt zunächst eine Abspaltung von Ammoniak, der ein schneller Verlust der verbleibenden Xanthinliganden folgt. Die für die Hauptzersetzungsreaktion bestimmte Aktivierungsenergie läßt vermuten, daß der Abbau der Xanthinliganden über eine Spaltung des Pyrimidinteils verläuft, der schnell die Abgabe des verbleibenden Imidazolteils folgt.
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![ocy](/content/u073115515011250/xxlarge1086.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) -![gcy](/content/u073115515011250/xxlarge1075.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![pcy](/content/u073115515011250/xxlarge1087.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) , ![kcy](/content/u073115515011250/xxlarge1082.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![ycy](/content/u073115515011250/xxlarge1099.gif) ![zcy](/content/u073115515011250/xxlarge1079.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![zcy](/content/u073115515011250/xxlarge1079.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![gcy](/content/u073115515011250/xxlarge1075.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![pcy](/content/u073115515011250/xxlarge1087.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) ![ucy](/content/u073115515011250/xxlarge1091.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![gcy](/content/u073115515011250/xxlarge1075.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) . ![scy](/content/u073115515011250/xxlarge1089.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![ucy](/content/u073115515011250/xxlarge1091.gif) ![chcy](/content/u073115515011250/xxlarge1095.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![pcy](/content/u073115515011250/xxlarge1087.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![bcy](/content/u073115515011250/xxlarge1073.gif) - (3-![mcy](/content/u073115515011250/xxlarge1084.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![pcy](/content/u073115515011250/xxlarge1087.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) (II) ![bcy](/content/u073115515011250/xxlarge1073.gif) -(9 -![mcy](/content/u073115515011250/xxlarge1084.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ) ![dcy](/content/u073115515011250/xxlarge1076.gif) -![acy](/content/u073115515011250/xxlarge1072.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![pcy](/content/u073115515011250/xxlarge1087.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) (II) ![dcy](/content/u073115515011250/xxlarge1076.gif) -![acy](/content/u073115515011250/xxlarge1072.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![pcy](/content/u073115515011250/xxlarge1087.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) (II) ![scy](/content/u073115515011250/xxlarge1089.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![chcy](/content/u073115515011250/xxlarge1095.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![pcy](/content/u073115515011250/xxlarge1087.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![khcy](/content/u073115515011250/xxlarge1093.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![ycy](/content/u073115515011250/xxlarge1099.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) , ![zcy](/content/u073115515011250/xxlarge1079.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![ycy](/content/u073115515011250/xxlarge1099.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![ucy](/content/u073115515011250/xxlarge1091.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![bcy](/content/u073115515011250/xxlarge1073.gif) ![ycy](/content/u073115515011250/xxlarge1099.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![vcy](/content/u073115515011250/xxlarge1074.gif) ![ycy](/content/u073115515011250/xxlarge1099.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![vcy](/content/u073115515011250/xxlarge1074.gif) ![shcy](/content/u073115515011250/xxlarge1096.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![khcy](/content/u073115515011250/xxlarge1093.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) ![ucy](/content/u073115515011250/xxlarge1091.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) . ![Kcy](/content/u073115515011250/xxlarge1050.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![gcy](/content/u073115515011250/xxlarge1075.gif) , ![ecy](/content/u073115515011250/xxlarge1101.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![gcy](/content/u073115515011250/xxlarge1075.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![vcy](/content/u073115515011250/xxlarge1074.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![tscy](/content/u073115515011250/xxlarge1094.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) , ![ocy](/content/u073115515011250/xxlarge1086.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![gcy](/content/u073115515011250/xxlarge1075.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![vcy](/content/u073115515011250/xxlarge1074.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![zcy](/content/u073115515011250/xxlarge1079.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![zhcy](/content/u073115515011250/xxlarge1078.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) , ![ucy](/content/u073115515011250/xxlarge1091.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![zcy](/content/u073115515011250/xxlarge1079.gif) ![ycy](/content/u073115515011250/xxlarge1099.gif) ![vcy](/content/u073115515011250/xxlarge1074.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) , ![tcy](/content/u073115515011250/xxlarge1090.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![zcy](/content/u073115515011250/xxlarge1079.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![ycy](/content/u073115515011250/xxlarge1099.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) ![ucy](/content/u073115515011250/xxlarge1091.gif) ![kcy](/content/u073115515011250/xxlarge1082.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![pcy](/content/u073115515011250/xxlarge1087.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![vcy](/content/u073115515011250/xxlarge1074.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![chcy](/content/u073115515011250/xxlarge1095.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![softcy](/content/u073115515011250/xxlarge1100.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![pcy](/content/u073115515011250/xxlarge1087.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![khcy](/content/u073115515011250/xxlarge1093.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![shchcy](/content/u073115515011250/xxlarge1097.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![pcy](/content/u073115515011250/xxlarge1087.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![pcy](/content/u073115515011250/xxlarge1087.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![rcy](/content/u073115515011250/xxlarge1088.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![vcy](/content/u073115515011250/xxlarge1074.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![vcy](/content/u073115515011250/xxlarge1074.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![yacy](/content/u073115515011250/xxlarge1103.gif) ![yucy](/content/u073115515011250/xxlarge1102.gif) ![shchcy](/content/u073115515011250/xxlarge1097.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![pcy](/content/u073115515011250/xxlarge1087.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![ucy](/content/u073115515011250/xxlarge1091.gif) ![yucy](/content/u073115515011250/xxlarge1102.gif) ![shchcy](/content/u073115515011250/xxlarge1097.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![vcy](/content/u073115515011250/xxlarge1074.gif) ![ycy](/content/u073115515011250/xxlarge1099.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![lcy](/content/u073115515011250/xxlarge1083.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![vcy](/content/u073115515011250/xxlarge1074.gif) ![shcy](/content/u073115515011250/xxlarge1096.gif) ![iecy](/content/u073115515011250/xxlarge1077.gif) ![jcy](/content/u073115515011250/xxlarge1081.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![mcy](/content/u073115515011250/xxlarge1084.gif) ![icy](/content/u073115515011250/xxlarge1080.gif) ![dcy](/content/u073115515011250/xxlarge1076.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![zcy](/content/u073115515011250/xxlarge1079.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![softcy](/content/u073115515011250/xxlarge1100.gif) ![ncy](/content/u073115515011250/xxlarge1085.gif) ![ocy](/content/u073115515011250/xxlarge1086.gif) ![chcy](/content/u073115515011250/xxlarge1095.gif) ![acy](/content/u073115515011250/xxlarge1072.gif) ![scy](/content/u073115515011250/xxlarge1089.gif) ![tcy](/content/u073115515011250/xxlarge1090.gif) .
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