Chemistry of naphthazarin derivatives. 7. Determination of structures of substituted 2,6(7)-dihydroxynaphthazarins by UV and IR spectroscopy |
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Authors: | Glazunov V P Tchizhova A Ya Shuvalova M I Anufriev V Ph |
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Institution: | (1) Pacific Institute of Bioorganic Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022 Vladivostok, Russian Federation;(2) Institute of Chemistry and Applied Ecology, Far Eastern State University, 27 ul. Octyabr'skaya, 690600 Vladivostok, Russian Federation |
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Abstract: | A set of substituted 2,6- and 2,7-dihydroxynaphthazarins were synthesized. The difference in the UV spectra of alkaline alcoholic solutions of 2,6- and 2,7-dihydroxynaphthazarins allows the reliable differentiation of the structures of these compounds. The IR spectra of 2,6- and 2,7-dihydroxynaphthazarins have characteristic nonoverlapping intervals of stretching vibration frequencies of the -hydroxy groups. Based on these spectral regularities, the data on cuculoquinone, which has been isolated previously from lichen Cetraria cucullata and has been identified as 7,7"-bis(3-ethyl-2,5,6,8-tetrahydroxynaphthalene-1,4-dione), were revised and the structure of 6,6"-bis(3-ethyl-2,5,7,8-tetrahydroxynaphthalene-1,4-dione) was assigned to this compound. |
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Keywords: | 2 6-dihydroxynaphthazarin 2 5 6 8-tetrahydroxy-1 4-naphthoquinone 2 7-dihydroxynaphthazarin 2 5 7 8-tetrahydroxy-1 4-naphthoquinone 7 7"-bis(3-ethyl-1 4 5 8-tetrahydroxynaphthalene-2 6-dione) 7 7"-bis(3-ethyl-2 5 6 8-tetrahydroxynaphthalene-1 4-dione) 6 6"-bis(3-ethyl-2 5 7 8-tetrahydroxynaphthalene-1 4-dione) electronic absorption spectra IR absorption spectra cuculoquinone Cetraria cucullata |
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