Structural and vibrational properties of dilute GaNxAs1−x(P1−x) |
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Authors: | Devki N Talwar |
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Institution: | Department of Physics, Indiana University of Pennsylvania, 56 Weyandt Hall, 975 Oakland Avenue, Indiana, PA 15705-1087, USA |
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Abstract: | We report a comprehensive analyzes of the Fourier transform infrared (FTIR) absorption and Raman scattering data on the structural and vibrational properties of dilute ternary GaAs1−xNx,GaP1−xNx] (x<0.03) alloys grown on GaAs GaP] by metal organic chemical vapor deposition (MOCVD) and solid source molecular beam epitaxy (MBE). By using realistic total energy and lattice dynamical calculations, the origin of experimentally observed N-induced vibrational features are characterized. Useful information is obtained about the structural stability, vibrational frequencies, lattice relaxations and compositional disorder in GaNAs (GaNP) alloys. At lower composition (x<0.015) most of the N atoms occupy the As P] sublattice {NAsNP]}—they prefer moving out of their substitutional sites to more energetically favorable locations at higher x. Our results for the N-isotopic shifts of local mode frequencies compare favorably well with the existing FTIR data. |
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Keywords: | FTIR spectroscopy Raman scattering Lattice relaxation Localized vibrational modes MBE MOCVD |
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