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Dimeric Tetrathiafulvalene Linked to pseudo‐ortho‐[2.2]Paracyclophane: Chiral Electrochromic Properties and Use as a Chiral Dopant |
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| Authors: | Kosuke Kobayakawa Dr. Masashi Hasegawa Hiroaki Sasaki Junta Endo Dr. Hideyo Matsuzawa Dr. Katsuya Sako Dr. Jun Yoshida Dr. Yasuhiro Mazaki |
| Affiliation: | 1. Department of Chemistry, School of Science, Kitasato University, Sagamihara, Kanagawa 252‐0373 (Japan), Fax: (+81)?426‐778‐8158;2. Department of Systems Management and Engineering, Nagoya Institute of Technology, Nagoya 466‐8555 (Japan) |
| Abstract: | A dimeric tetrathiafulvalene installed into a chiral pseudo‐ortho‐[2.2]paracyclophane framework was synthesized as a novel chiral electrochromic material. This compound exhibited pronounced chiroptical properties in the UV‐Vis‐NIR range depending on its redox states without racemization. Each enantiomer was examined as a chiral dopant for nematic liquid crystals (LCs), and the induced helicity of the LC solvent was in accord with that of the tetrathiafulvalene compound. |
| Keywords: | chirality chiroptical properties cyclophanes electrochromism tetrathiafulvalene |