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Half-sandwich trihydrido ruthenium complexes
Authors:Alexandr L Osipov  Lyudmila G Kuzmina  Dmitry A Lemenovskii  Georgii I Nikonov
Institution:a Chemistry Department, Moscow State University, Vorob’evy Gory, 119992 Moscow, Russia
b Chemistry Department, Brock University, 500 Glenridge Ave., St. Catharines, ON, Canada L2S 3A1
c Institute of General and Inorganic Chemistry, RAS, Leninskii Prosp. 31, 119991 Moscow, Russia
d Chemistry Department, University of Durham, South Road, Durham DH1 3LE, UK
e Institut de Chimie, Université de Neuchâtel, Case Postale 158, CH-2009 Neuchâtel, Switzerland, UK
Abstract:This paper reports facile preparation of half-sandwich trihydrido complexes of ruthenium based on the reactions of the readily available precursors Cp(R3P)Ru(NCCH3)2]PF6] with LiAlH4. The target complexes were characterized by spectroscopic methods and X-ray structure analysis of View the MathML source.
Keywords:Ruthenium  Hydride
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