The first chelating olefin: Solid-state structure of bis-(η-4-phenyl-η-1-butene)silver (I) tetrafluoroborate |
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| Authors: | DR Whitcomb M Rajeswaran |
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| Institution: | a Carestream Health, 1 Imation Way, Oakdale, MN 55128, USA
b Eastman Kodak Company, 1999 Lake Avenue, Rochester, NY 14650-2106, USA |
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| Abstract: | A complex of 4-phenyl-1-butene with silver ion has been prepared by mixing silver (I) tetrafluoroborate with the neat ligand at room temperature. Purification by crystallization produces a stable complex characterized by solid-state structure. The bis-(η1-4-phenyl-η2-1-butene)silver (I) tetrafluoroborate complex contains a pair of olefin ligands that chelate a single silver atom via both olefin and aromatic Ag-C bonds. This is the first chelated organometallic silver complex reported in the literature assembled with only Ag-C bonds. |
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| Keywords: | Silver Olefin 4-Phenyl-1-butene Chelate Silver-carbon bond Structure |
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