New route to alkylaluminum hydroxides via hydrolysis of cyclopentadienylaluminum complexes |
| |
| Authors: | Kinga Leszczyńska Janusz Zachara Magdalena ?o? |
| |
| Institution: | Faculty of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland |
| |
| Abstract: | A novel, very simple and effective synthetic method for the formation of alkylaluminum complexes with terminal hydroxy group via hydrolysis of cyclopentadienylaluminum compounds has been found. Investigations of the hydrolysis of cyclopentadienylaluminum complexes (L)Al(Me)Cp (1) and (L)Al(Et)Cp (2) (L = HC(CMe)(2,6-iPr2C6 H3N)]2) have shown that the reaction leads to the formation of (L)Al(Me)OH (3) and (L)Al(Et)OH (4), respectively. The high selectivity of the hydrolysis was revealed. The crystal structures of 1, 2 and 4 were determined. |
| |
| Keywords: | Alkylaluminum hydroxides Cyclopentadienylaluminum β-Diketiminate Hydrolysis Structure |
| 本文献已被 ScienceDirect 等数据库收录！ |
