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Fe(Cp)2PF6: An efficient catalyst for cyanosilylation of carbonyl compounds under solvent free condition |
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| Authors: | Noor-ul H. Khan Santosh Agrawal Rukhsana I. Kureshy Sayed H.R. Abdi Surendra Singh Raksh V. Jasra |
| Affiliation: | Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (CSMCRI), G.B. Marg, Bhavnagar 364 002, Gujarat, India |
| Abstract: | An efficient method for the addition of trimethylsilyl cyanide (TMSCN) to various aldehydes and ketones has been described using Fe(Cp)2PF6 (2.5 mol%) as a catalyst under solvent free condition. Excellent yields of trimethylsilylether of cyanohydrin up to (94%) was achieved within 10 min. |
| Keywords: | Carbonyl compounds Fe(Cp)2PF6 Solvent free synthesis Cyanosilylation Catalysis |
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