A new dirhodium tetraacetate carbenoid: Synthesis, crystal structure and catalytic application |
| |
| Authors: | Sung Jae Na Nhat-Nguyen Bui Hye-Young Jang |
| |
| Institution: | a Department of Molecular Science and Technology, Ajou University, Suwon 442-749, Republic of Korea
b Division of Energy Systems Research, Ajou University, Suwon 442-749, Republic of Korea |
| |
| Abstract: | A new dirhodium tetraacetate II involving 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene I was synthesized and characterized by general spectroscopic tools in the solution state as well as single X-ray crystallographic analysis in the solid state. The catalytic activity of dirhodium tetraacetate carbenoid II was tested for the allylic oxidation, and the improved reactivity to the allylic oxidation was observed compared to that of Rh2(OAc)4. The different electrochemical properties of dirhodium tetraacetate carbenoid II and Rh2(OAc)4 were compared via cyclic voltammetry. |
| |
| Keywords: | Dirhodium tetraacetate Carbene Allylic oxidation Electron donor |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
