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Different products in the reaction of the alcohols with cyclic and acyclic 1,3-dicarbonyl compounds:K5CoW12O40 as an electron transfer nano catalyst
Authors:Ezzat Rafiee  Masoud Kahrizi  Mohammad Joshaghani
Affiliation:Department of Chemistry, Razi University, Kermanshah 67149, Iran
Abstract:K5CoW12O40 was used as a highly effective catalyst for the benzylation of 1, 3-dicarbonyl compounds. β-Keto enol ethers were obtained when cyclic 1, 3–dicarbonyl compounds used in this conditions instead of linear ones. The present methodology offers a practical, simple, mild, environmentally friendly, and time-saving method for etherification. Very low loading of catalyst, ease of workup, ease of handling, and reusability of catalyst are other advantages of this catalyst.
Keywords:Benzylation   Etherification   β-Keto enol ethers   Nano catalyst   Polyoxometalate  
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