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Structure and behaviour of the free radicals generated in gamma irradiated amino acid and iminodiacetic acid derivatives
Authors:Osmano?lu Semsettin  Ayd?n Murat  Osmano?lu Y Emre  Dicle I Ye?im  Ba?kan M Halim
Institution:a Faculty of Science, Dicle University, Diyarbakır, Turkey;b Faculty of Education, Adıyaman University, TR 02040-Adıyaman, Turkey;c Faculty of Education, Dicle University, Diyarbakır, Turkey
Abstract:An EPR study has been carried out to investigate the structure and behaviour of the free radical formed γ-irradiated l-alaninamide hydrochloride, dl-glutamic acid monohydrate and N-(2-carboxyethyl) iminodiacetic acid powders at room temperature. The observed paramagnetic species have been attributed to the CH(3)?HCONH(2), HOOCCH(2)CH(2)?HCOOH and HOOCCH(2)CH(2)N?HCH(2)(COOH)(2) radicals, respectively. Some spectroscopic properties and suggestions concerning possible structure of the radicals were also discussed in this study.
Keywords:Gamma irradiation  EPR  Free radicals  Amino acids
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