Structure and behaviour of the free radicals generated in gamma irradiated amino acid and iminodiacetic acid derivatives |
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Authors: | Osmano?lu Semsettin Ayd?n Murat Osmano?lu Y Emre Dicle I Ye?im Ba?kan M Halim |
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Institution: | a Faculty of Science, Dicle University, Diyarbakır, Turkey;b Faculty of Education, Adıyaman University, TR 02040-Adıyaman, Turkey;c Faculty of Education, Dicle University, Diyarbakır, Turkey |
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Abstract: | An EPR study has been carried out to investigate the structure and behaviour of the free radical formed γ-irradiated l-alaninamide hydrochloride, dl-glutamic acid monohydrate and N-(2-carboxyethyl) iminodiacetic acid powders at room temperature. The observed paramagnetic species have been attributed to the CH(3)?HCONH(2), HOOCCH(2)CH(2)?HCOOH and HOOCCH(2)CH(2)N?HCH(2)(COOH)(2) radicals, respectively. Some spectroscopic properties and suggestions concerning possible structure of the radicals were also discussed in this study. |
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Keywords: | Gamma irradiation EPR Free radicals Amino acids |
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