| 盐酸三甲胺三氧化铬／硅胶对醇类化合物的氧化研究 |
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| 引用本文： | 张贵生,张松林.盐酸三甲胺三氧化铬／硅胶对醇类化合物的氧化研究[J].合成化学,1997,5(3):303-304,302. |
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| 作者姓名： | 张贵生 张松林 |
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| 作者单位： | 河南师范大学化学系 |
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| 基金项目： | 国家及河南省自然科学基金 |
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| 摘 要： | 报道了盐酸三甲胺三氧化铬／硅胶对醇类化合物的氧化反应。盐酸三甲胺三氧化铬／硅胶可在多种介质中氧化伯醇和仲醇成为相应的醛或酮，反应条件温和、操作简单、收率高。
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| 关 键 词： | 盐酸三甲胺 三氧化铬 醇 氧化 醛 酮 |
Oxidation of Alcohols with Trimethylammonium Chlorochromate/Silica Gel |
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| Zhang,Gui Sheng Zhang,Song Lin Cai,Kun.Oxidation of Alcohols with Trimethylammonium Chlorochromate/Silica Gel[J].Chinese Journal of Synthetic Chemistry,1997,5(3):303-304,302. |
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| Authors: | Zhang Gui Sheng Zhang Song Lin Cai Kun |
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| Abstract: | This paper reported the oxidation of alcohols with trimethylammonium chlorochromate/silica gel. Primary and secondary alcohols were oxidized to corresponding aldehydes and ketones with high yields. The oxidation conditions were mild and the products of oxidation were easily separated. The oxidation of alcohols with this reagent can be carried out easily in some of selected solvents. |
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| Keywords: | Trimethylammonium chlorochromate/silica gel Alcohols Oxidation |
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