Access to C(sp3)-C(sp2) and C(sp2)-C(sp2) bond formation via sequential intermolecular carbopalladation of multiple carbon-carbon bonds |
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| Authors: | Wen Yanmei Huang Liangbin Jiang Huanfeng |
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| Institution: | School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China. |
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| Abstract: | A synthetic strategy of 4-benzyl-substituted 1,3-butadiene derivatives through Pd-catalyzed three-component coupling reaction of benzyl chlorides, alkynes, and monosubstituted alkenes is described. This tandem coupling reaction forms a C(sp(3))-C(sp(2)) bond and a C(sp(2))-C(sp(2)) bond sequentially in a single-step operation. |
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